Collective Advantages in Finite-Time Thermodynamics.

A central task in finite-time thermodynamics is to minimize the excess or dissipated work W_{diss} when manipulating the state of a system immersed in a thermal bath. We consider this task for an N-body system whose constituents are identical and uncorrelated at the beginning and end of the process. In the regime of slow but finite-time processes, we show that W_{diss} can be dramatically reduced by considering collective protocols in which interactions are suitably created along the protocol. This can even lead to a sublinear growth of W_{diss} with N: W_{diss}∝N^{x} with x<1; to be contrasted to the expected W_{diss}∝N satisfied in any noninteracting protocol. We derive the fundamental limits to such collective advantages and show that x=0 is in principle possible; however, it requires long-range interactions. We explore collective processes with spin models featuring two-body interactions and achieve noticeable gains under realistic levels of control in simple interaction architectures. As an application of these results, we focus on the erasure of information in finite time and prove a faster convergence to Landauer's bound.

Critical Quantum Metrology Assisted by Real-Time Feedback Control.

We investigate critical quantum metrology, that is, the estimation of parameters in many-body systems close to a quantum critical point, through the lens of Bayesian inference theory. We first derive a no-go result stating that any nonadaptive strategy will fail to exploit quantum critical enhancement (i.e., precision beyond the shot-noise limit) for a sufficiently large number of particles N whenever our prior knowledge is limited. We then consider different adaptive strategies that can overcome this no-go result and illustrate their performance in the estimation of (i) a magnetic field using a probe of 1D spin Ising chain and (ii) the coupling strength in a Bose-Hubbard square lattice. Our results show that adaptive strategies with real-time feedback control can achieve sub-shot-noise scaling even with few measurements and substantial prior uncertainty.

Operational Definition of the Temperature of a Quantum State.

Temperature is usually defined for physical systems at thermal equilibrium. Nevertheless one may wonder if it would be possible to attribute a meaningful notion of temperature to an arbitrary quantum state, beyond simply the thermal (Gibbs) state. In this Letter, we propose such a notion of temperature considering an operational task, inspired by the zeroth law of thermodynamics. Specifically, we define two effective temperatures for quantifying the ability of a quantum system to cool down or heat up a thermal environment. In this way we can associate an operationally meaningful notion of temperature to any quantum density matrix. We provide general expressions for these effective temperatures, for both single- and many-copy systems, establishing connections to concepts previously discussed in the literature. Finally, we consider a more sophisticated scenario where the heat exchange between the system and the thermal environment is assisted by a quantum reference frame. This leads to an effect of "coherent quantum catalysis," where the use of a coherent catalyst allows for exploiting quantum energetic coherences in the system, now leading to much colder or hotter effective temperatures. We demonstrate our findings using a two-level atom coupled to a single mode of the electromagnetic field.

Fundamental Limits in Bayesian Thermometry and Attainability via Adaptive Strategies.

We investigate the limits of thermometry using quantum probes at thermal equilibrium within the Bayesian approach. We consider the possibility of engineering interactions between the probes in order to enhance their sensitivity, as well as feedback during the measurement process, i.e., adaptive protocols. On the one hand, we obtain an ultimate bound on thermometry precision in the Bayesian setting, valid for arbitrary interactions and measurement schemes, which lower bounds the error with a quadratic (Heisenberg-like) scaling with the number of probes. We develop a simple adaptive strategy that can saturate this limit. On the other hand, we derive a no-go theorem for nonadaptive protocols that does not allow for better than linear (shot-noise-like) scaling even if one has unlimited control over the probes, namely, access to arbitrary many-body interactions.

Experimental Verification of the Work Fluctuation-Dissipation Relation for Information-to-Work Conversion.

We study experimentally work fluctuations in a Szilard engine that extracts work from information encoded as the occupancy of an electron level in a semiconductor quantum dot. We show that as the average work extracted per bit of information increases toward the Landauer limit k_{B}Tln2, the work fluctuations decrease in accordance with the work fluctuation-dissipation relation. We compare the results to a protocol without measurement and feedback and show that when no information is used, the work output and fluctuations vanish simultaneously, contrasting the information-to-energy conversion case where increasing amount of work is produced with decreasing fluctuations. Our study highlights the importance of fluctuations in the design of information-to-work conversion processes.

Minimally Dissipative Information Erasure in a Quantum Dot via Thermodynamic Length.

In this Letter, we explore the use of thermodynamic length to improve the performance of experimental protocols. In particular, we implement Landauer erasure on a driven electron level in a semiconductor quantum dot, and compare the standard protocol in which the energy is increased linearly in time with the one coming from geometric optimization. The latter is obtained by choosing a suitable metric structure, whose geodesics correspond to optimal finite-time thermodynamic protocols in the slow driving regime. We show experimentally that geodesic drivings minimize dissipation for slow protocols, with a bigger improvement as one approaches perfect erasure. Moreover, the geometric approach also leads to smaller dissipation even when the time of the protocol becomes comparable with the equilibration timescale of the system, i.e., away from the slow driving regime. Our results also illustrate, in a single-electron device, a fundamental principle of thermodynamic geometry: optimal finite-time thermodynamic protocols are those with constant dissipation rate along the process.

Quantum Speed-Up in Collisional Battery Charging.

We present a collision model for the charging of a quantum battery by identical nonequilibrium qubit units. When the units are prepared in a mixture of energy eigenstates, the energy gain in the battery can be described by a classical random walk, where both average energy and variance grow linearly with time. Conversely, when the qubits contain quantum coherence, interference effects buildup in the battery and lead to a faster spreading of the energy distribution, reminiscent of a quantum random walk. This can be exploited for faster and more efficient charging of a battery initialized in the ground state. Specifically, we show that coherent protocols can yield higher charging power than any possible incoherent strategy, demonstrating a quantum speed-up at the level of a single battery. Finally, we characterize the amount of extractable work from the battery through the notion of ergotropy.

Joint statistics of work and entropy production along quantum trajectories.

In thermodynamics, entropy production and work quantify irreversibility and the consumption of useful energy, respectively, when a system is driven out of equilibrium. For quantum systems, these quantities can be identified at the stochastic level by unravelling the system's evolution in terms of quantum jump trajectories. We here derive a general formula for computing the joint statistics of work and entropy production in Markovian driven quantum systems, whose instantaneous steady states are of Gibbs form. If the driven system remains close to the instantaneous Gibbs state at all times, then we show that the corresponding two-variable cumulant generating function implies a joint detailed fluctuation theorem so long as detailed balance is satisfied. As a corollary, we derive a modified fluctuation-dissipation relation (FDR) for the entropy production alone, applicable to transitions between arbitrary steady states, and for systems that violate detailed balance. This FDR contains a term arising from genuinely quantum fluctuations, and extends an analogous relation from classical thermodynamics to the quantum regime.

Thermodynamic Uncertainty Relation in Slowly Driven Quantum Heat Engines.

Thermodynamic uncertainty relations express a trade-off between precision, defined as the noise-to-signal ratio of a generic current, and the amount of associated entropy production. These results have deep consequences for autonomous heat engines operating at steady state, imposing an upper bound for their efficiency in terms of the power yield and its fluctuations. In the present Letter we analyze a different class of heat engines, namely, those which are operating in the periodic slow-driving regime. We show that an alternative TUR is satisfied, which is less restrictive than that of steady-state engines: it allows for engines that produce finite power, with small power fluctuations, to operate close to reversibility. The bound further incorporates the effect of quantum fluctuations, which reduces engine efficiency relative to the average power and reliability. We finally illustrate our findings in the experimentally relevant model of a single-ion heat engine.

Geometric Optimisation of Quantum Thermodynamic Processes.

Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines.

Minimizing Backaction through Entangled Measurements.

When an observable is measured on an evolving coherent quantum system twice, the first measurement generally alters the statistics of the second one, which is known as measurement backaction. We introduce, and push to its theoretical and experimental limits, a novel method of backaction evasion, whereby entangled collective measurements are performed on several copies of the system. This method is inspired by a similar idea designed for the problem of measuring quantum work [Perarnau-Llobet et al., Phys. Rev. Lett. 118, 070601 (2017)PRLTAO0031-900710.1103/PhysRevLett.118.070601]. By using entanglement as a resource, we show that the backaction can be extremely suppressed compared to all previous schemes. Importantly, the backaction can be eliminated in highly coherent processes.

Optimal Cycles for Low-Dissipation Heat Engines.

We consider the optimization of a finite-time Carnot engine characterized by small dissipations. We bound the power with a simple inequality and show that the optimal strategy is to perform small cycles around a given working point, which can be, thus, chosen optimally. Remarkably, this optimal point is independent of the figure of merit combining power and efficiency that is being maximized. Furthermore, for a general class of dissipative dynamics the maximal power output becomes proportional to the heat capacity of the working substance. Since the heat capacity can scale supraextensively with the number of constituents of the engine, this enables us to design optimal many-body Carnot engines reaching maximum efficiency at finite power per constituent in the thermodynamic limit.

Work Fluctuations in Slow Processes: Quantum Signatures and Optimal Control.

An important result in classical stochastic thermodynamics is the work fluctuation-dissipation relation (FDR), which states that the dissipated work done along a slow process is proportional to the resulting work fluctuations. We show that slowly driven quantum systems violate this FDR whenever quantum coherence is generated along the protocol, and we derive a quantum generalization of the work FDR. The additional quantum terms in the FDR are found to lead to a non-Gaussian work distribution. Fundamentally, our result shows that quantum fluctuations prohibit finding slow protocols that minimize both dissipation and fluctuations simultaneously, in contrast to classical slow processes. Instead, we develop a quantum geometric framework to find processes with an optimal trade-off between the two quantities.

Experimentally reducing the quantum measurement back action in work distributions by a collective measurement.

In quantum thermodynamics, the standard approach to estimating work fluctuations in unitary processes is based on two projective measurements, one performed at the beginning of the process and one at the end. The first measurement destroys any initial coherence in the energy basis, thus preventing later interference effects. To decrease this back action, a scheme based on collective measurements has been proposed by Perarnau-Llobet et al. Here, we report its experimental implementation in an optical system. The experiment consists of a deterministic collective measurement on two identically prepared qubit states, encoded in the polarization and path degree of a single photon. The standard two-projective measurement approach is also experimentally realized for comparison. Our results show the potential of collective schemes to decrease the back action of projective measurements, and capture subtle effects arising from quantum coherence.

Dynamics of quantum measurements employing two Curie-Weiss apparatuses.

Two types of quantum measurements, measuring the spins of an entangled pair and attempting to measure a spin at either of two positions, are analysed dynamically by apparatuses of the Curie-Weiss type. The outcomes comply with the standard postulates.This article is part of the themed issue 'Second quantum revolution: foundational questions'.

Quantum Thermal Machine as a Thermometer.

We propose the use of a quantum thermal machine for low-temperature thermometry. A hot thermal reservoir coupled to the machine allows for simultaneously cooling the sample while determining its temperature without knowing the model-dependent coupling constants. In its most simple form, the proposed scheme works for all thermal machines that perform at Otto efficiency and can reach Carnot efficiency. We consider a circuit QED implementation that allows for precise thermometry down to ∼15 mK with realistic parameters. Based on the quantum Fisher information, this is close to the optimal achievable performance. This implementation demonstrates that our proposal is particularly promising in systems where thermalization between different components of an experimental setup cannot be guaranteed.

No-Go Theorem for the Characterization of Work Fluctuations in Coherent Quantum Systems.

An open question of fundamental importance in thermodynamics is how to describe the fluctuations of work for quantum coherent processes. In the standard approach, based on a projective energy measurement both at the beginning and at the end of the process, the first measurement destroys any initial coherence in the energy basis. Here we seek extensions of this approach which can possibly account for initially coherent states. We consider all measurement schemes to estimate work and require that (i) the difference of average energy corresponds to average work for closed quantum systems and that (ii) the work statistics agree with the standard two-measurement scheme for states with no coherence in the energy basis. We first show that such a scheme cannot exist. Next, we consider the possibility of performing collective measurements on several copies of the state and prove that it is still impossible to simultaneously satisfy requirements (i) and (ii). Nevertheless, improvements do appear, and in particular, we develop a measurement scheme that acts simultaneously on two copies of the state and allows us to describe a whole class of coherent transformations.

Energetics of correlations in interacting systems.

A fundamental connection between thermodynamics and information theory arises from the fact that correlations exhibit an inherent work value. For noninteracting systems this translates to a work cost for establishing correlations. Here we investigate the relationship between work and correlations in the presence of interactions that cannot be controlled or removed. For such naturally coupled systems, which are correlated even in thermal equilibrium, we determine general strategies that can reduce the work cost of correlations, and illustrate these for a selection of exemplary physical systems.

Most energetic passive states.

Passive states are defined as those states that do not allow for work extraction in a cyclic (unitary) process. Within the set of passive states, thermal states are the most stable ones: they maximize the entropy for a given energy, and similarly they minimize the energy for a given entropy. Here we find the passive states lying in the other extreme, i.e., those that maximize the energy for a given entropy, which we show also minimize the entropy when the energy is fixed. These extremal properties make these states useful to obtain fundamental bounds for the thermodynamics of finite-dimensional quantum systems, which we show in several scenarios.

Thermodynamics of creating correlations: Limitations and optimal protocols.

We establish a rigorous connection between fundamental resource theories at the quantum scale. Correlations and entanglement constitute indispensable resources for numerous quantum information tasks. However, their establishment comes at the cost of energy, the resource of thermodynamics, and is limited by the initial entropy. Here, the optimal conversion of energy into correlations is investigated. Assuming the presence of a thermal bath, we establish general bounds for arbitrary systems and construct a protocol saturating them. The amount of correlations, quantified by the mutual information, can increase at most linearly with the available energy, and we determine where the linear regime breaks down. We further consider the generation of genuine quantum correlations, focusing on the fundamental constituents of our universe: fermions and bosons. For fermionic modes, we find the optimal entangling protocol. For bosonic modes, we show that while Gaussian operations can be outperformed in creating entanglement, their performance is optimal for high energies.